Synthesis of Dimethyl Selenone and Studies on the BiomethylationIntermediates of Selenium Reduction and Methylation
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SYNTHESIS AND THERMAL REARRANGEMENT OF OXYGEN HETEROCYCLIC SPIRANS
Thermal rearrangement of spirans (14) and (31) yields the xanthones (16,34) and diphenylrnethane (15, 32), respectively. The structure for xanthone (16), isolated from thermolysis, has been established by reduction to xanthene (20) followed by reoxidation to give xanthone (16). Alternatively, methylation of the diphenylmethane (15) followed by heating with selenium dioxide also yields xant...
متن کاملPage numbering has changed in this Adobe Acrobat Document TOXICITY COMPARISON OF SELENIUM OXYANIONS WITH A PROPOSED BIOMETHYLATION INTERMEDIATE DIMETHYL SELENONE IN A MINIMAL MEDIUM ACCOMPANIED BY SELENIUM DISTRIBUTION ANALYSIS
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